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| mrgjones |
May 11 2011, 09:57 AM
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#1
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Member ![]() ![]() Group: Members Posts: 91 Joined: 23-November 09 From: Monterey Member No.: 11,062 Region Association: Northern California |
Alright. There are a lot of products on the market that promise to remove rust and prevent it from coming back. From reading the threads it seems the opinions on this forum are as varied as the products themselves. This thread is about making a convincing argument... or a ludicrous allegation, which ever you find appropriate. Horror stories are welcome but please limit yourselves to the chemical rust abatement theme already established. For you slow starters, here is your motivation.
(IMG:style_emoticons/default/piratenanner.gif) (IMG:style_emoticons/default/piratenanner.gif) (IMG:style_emoticons/default/piratenanner.gif) (IMG:style_emoticons/default/piratenanner.gif) (IMG:style_emoticons/default/piratenanner.gif) (IMG:style_emoticons/default/piratenanner.gif) (IMG:style_emoticons/default/cheer.gif) (IMG:style_emoticons/default/cheer.gif) (IMG:style_emoticons/default/cheer.gif) (IMG:style_emoticons/default/cheer.gif) (IMG:style_emoticons/default/piratenanner.gif) (IMG:style_emoticons/default/piratenanner.gif) (IMG:style_emoticons/default/piratenanner.gif) (IMG:style_emoticons/default/piratenanner.gif) (IMG:style_emoticons/default/piratenanner.gif) (IMG:style_emoticons/default/piratenanner.gif) |
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| Katmanken |
May 12 2011, 11:35 AM
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#2
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You haven't seen me if anybody asks... ![]() ![]() ![]() ![]() Group: Members Posts: 4,738 Joined: 14-June 03 From: USA Member No.: 819 Region Association: Upper MidWest |
I think the electrolytic process is the way to go. There is a place in Cincinnati on Northland Blvd near the Porsche dealership called American Metal Refinishing that seems to use it and can do a whole car in their tank. I use it at home for everything with no problems. Per the line of sight, yes, but a little creativity never hurt. Can you say coathanger electrode inside a tube? American Metal refinishing can get inside of the cavities if you request it. They removed the paint, inner foam, and all of the the rust from my trunk for $60-$70. The worst that I had to do was slap the rear lip area of the trunk to knock the chunks of blackened and killed rust out of the latch hole. Not sure what process they used as the blackened rust bubbles aren't created with the electrolytic process, but it worked.
Per the hydrogen embrittlement concerns, do your metallurgy. I think you will find that hydrogen embrittlement affects really HSLA ( high strength low alloy) steels or hardened steels, and doesn't do much of anything with non-heat treated steels like the mild steels. For those of you that don't know, mild steels were the automobile steel of choice due to the ductility, low cost and ease of formability before the late 70s. The Japanese pioneered the use of HSLA steels in the mid to late 70's which made the body panels both harder and thinner due to heat treating. HSLA steels are succeptable to hydrogen embrittlement and reduced strength from heating which is why they don't recommend welding late model cars. HSLA steels are also highly prone to rust as witnessed by the notoriety of 70's and 80's Hondas as rustbuckets with shock towers shooting through the hoods, gaping holes under the bumpers, and windshield pillars rusting through for your rollover pleasure. No, I wouldn't throw a nitrided crank in the tank, and ball bearings may fall off the electrolytic list, but I have seen pristine cast iron engine blocks as they come out of the tank. Yes, it was my amazing rusting-before-your-eyes POS Honda that made this engineer research the mild steel vs HSLA topic. |
| Madswede |
May 12 2011, 12:39 PM
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#3
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Flat Out Driver ![]() ![]() ![]() Group: Members Posts: 853 Joined: 13-September 06 From: Rio Rancho NM Member No.: 6,831 Region Association: Rocky Mountains |
Per the hydrogen embrittlement concerns, do your metallurgy. I think you will find that hydrogen embrittlement affects really HSLA ( high strength low alloy) steels or hardened steels, and doesn't do much of anything with non-heat treated steels like the mild steels. For those of you that don't know, mild steels were the automobile steel of choice due to the ductility, low cost and ease of formability before the late 70s. The Japanese pioneered the use of HSLA steels in the mid to late 70's which made the body panels both harder and thinner due to heat treating. HSLA steels are succeptable to hydrogen embrittlement and reduced strength from heating which is why they don't recommend welding late model cars. HSLA steels are also highly prone to rust as witnessed by the notoriety of 70's and 80's Hondas as rustbuckets with shock towers shooting through the hoods, gaping holes under the bumpers, and windshield pillars rusting through for your rollover pleasure. No, I wouldn't throw a nitrided crank in the tank, and ball bearings may fall off the electrolytic list, but I have seen pristine cast iron engine blocks as they come out of the tank. (IMG:style_emoticons/default/agree.gif) You took the words right out of my mouth! (IMG:style_emoticons/default/beerchug.gif) I would emphasize that the most common cause of hydrogen embrittlement in steel is where there is high pressure and relatively high temperatures during the manufacturing process, both of which will not exist in an electrolytic solution. A high concentration gradient could drive H2 to diffuse into steel as well, but the reduction reaction isn't fast enough (and hydrogen is the lightest gas there is) that it won't be in very high concentration in the solution such that there would be that concentration gradient as a driving force for significant diffusion. Also, the "line of sight" thing is true in a way. For whatever reason this occurs (I suspect its more of a rate of reaction due to the electrical field between the anode and cathode as opposed to not working at all), from my own research it seems a large enough tank and spacing between the anode and cathode solves this problem to a large extent. Anyway, I still think electrolysis would be a promising method for that special case where the car/parts in question have lotsa rust all over but not enough to ruin the structural integrity of the part (in other words cut it out and replace it). |
mrgjones WhO's THE BEST May 11 2011, 09:57 AM
sww914 Rust Mort. May 11 2011, 10:12 AM
mrgjones
Rust Mort.
Rust Mort. I've never heard of it... May 11 2011, 10:30 AM
PeeGreen 914 I believe Ospho is one of the best out there. Amaz... May 11 2011, 10:14 AM
mrgjones
I believe Ospho is one of the best out there. Ama... May 11 2011, 10:22 AM
Bartlett 914 Rust Bullet....NOT May 11 2011, 10:22 AM
mrgjones
Rust Bullet....NOT
Rust bullet has a pretty con... May 11 2011, 10:24 AM
Bartlett 914
Rust Bullet....NOT
Rust bullet has a pretty co... May 11 2011, 02:06 PM
PeeGreen 914 Rust mort is good but you have to rinse it well. T... May 11 2011, 10:42 AM
ArtechnikA For light rust, tin snips.
For heavy rust, plasma ... May 11 2011, 11:29 AM
bigkensteele
You think we have rust problems? (We do...) But t... May 11 2011, 08:33 PM
underthetire Loctite Extend. Been using it for years. But i agr... May 11 2011, 11:37 AM
dlestep ...I took my body down to metal and treated it wit... May 11 2011, 12:23 PM
ArtechnikA
I trust rust converter, like I trust the curing p... May 11 2011, 12:41 PM
enderw88 I used Eastwood Rust Encapsulator on the steel fra... May 11 2011, 02:39 PM
Ductech
I used Eastwood Rust Encapsulator on the steel fr... May 11 2011, 03:49 PM
enderw88
I used Eastwood Rust Encapsulator on the steel f... May 11 2011, 06:39 PM
Madswede I wonder if anyone has done a large-scale electrol... May 11 2011, 06:16 PM
mrgjones
I wonder if anyone has done a large-scale electro... May 11 2011, 07:36 PM
silver74insocal anyone have experience with naval jelly? :popcorn: May 11 2011, 06:26 PM
sean_v8_914 "WhO's THE BEST, rust remover/ encapsulat... May 11 2011, 09:26 PM
ewdysar
"WhO's THE BEST, rust remover/ encapsula... May 12 2011, 01:40 AM
mrgjones I've been kind of eying the por 15 products bu... May 11 2011, 09:58 PM
avidfanjpl Silver in Socal
Stay away forever from Naval Jell... May 12 2011, 01:17 AM
sean_v8_914 yup. I bumped it. Perry gives a good write up May 12 2011, 07:31 AM
mrgjones Just finished reading the other thread. There... May 12 2011, 08:48 AM
scotty b
Just finished reading the other thread. There... May 12 2011, 08:58 AM
ArtechnikA OK as long as we're driving down this path - w... May 12 2011, 12:46 PM
zymurgist I've read good things about electrolysis on ol... May 12 2011, 01:14 PM
kwales When I went to get my trunk done at American Metal... May 12 2011, 05:29 PM
mrgjones
I've done electroless nickel plating on a l... May 12 2011, 06:48 PM
Madswede As a chemical engineer kinda looking to branch out... May 13 2011, 12:55 AM
dlestep ...too late now, buddy...I purchased the property,... May 13 2011, 10:03 AM
dlestep
...too late now, buddy...I purchased the property... May 14 2011, 07:29 AM
kwales One other thing with the electrolysis process is t... May 14 2011, 12:47 PM
mrgjones This has got me thinking how I can build a giant t... May 14 2011, 01:26 PM
kwales On the first try, I rusted a positive electrode st... May 14 2011, 04:52 PM
mrgjones
On the first try, I rusted a positive electrode s... May 18 2011, 09:25 AM
mrgjones
I've been using rebar welded into a grid for ... May 18 2011, 09:31 AM
rohar There's a couple of sponges, a 2" steel s... May 17 2011, 08:07 PM
rohar Ok, so I've had it running on 5 amps for about... May 17 2011, 09:18 PM
sean_v8_914 this thread has taken a very interesting turn.
roh... May 18 2011, 07:50 AM
rohar I took picks, I'll have them posted shortly. ... May 18 2011, 08:42 AM
sean_v8_914 maybe a pneumatic scaling gun would help May 18 2011, 08:59 AM
rohar It's not the crud, there's a bit of a curv... May 18 2011, 09:13 AM
rohar Before, I've seen much worse:
http://www.914w... May 18 2011, 09:41 AM
rohar I let it cook for 2 hours last time, that pulled a... May 18 2011, 11:08 AM
rohar Alright, I couldn't wait. I pulled everything... May 18 2011, 11:44 AM
dlestep ...I am really liking this...if you could be so ki... May 18 2011, 11:51 AM
rohar More pics to follow, putting it on for another coo... May 18 2011, 12:18 PM
rohar After cooking about 4 total hours. I have maybe 1... May 18 2011, 12:56 PM
kwales Actuallly, if you do it long enough, the black tur... May 18 2011, 08:43 PM
rohar I'm in good shape. I went with a bigger anode... May 18 2011, 08:57 PM![]() ![]() |
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