aluminum and copper are both pretty good heat conductors but even my rubber hoses put way to much heat inside the cabin when in the rockers.
the Gates (I think it is called green stripe) hoses is very tough, thick and re-inforced no corrosion issues is a bonus. but run it under the car. that is what a major conversion company is now doing. You can get this "bullet proof hose from hot rod shops or West Marine supply
rubber is just fine, even if it did get draged on a bump, face it, youtires are made of rubber, and this stuff seems to be near as tuff as tire rubber.
the risk of a show stopping cruch of a metal pipe is too much for me, plus the rubber hose is very very easy to bend to fit verses a metal pipe!
easy install, and tough and a decent price, cant beat that, plus under your car you have no worry at all of leaks getting in the cabin nor the excessive heat, my little V6 car dumps way to much heat in the cabin with the hose in the rockers,
plus you will need some right angle metallic couplings to transition the hose from teh heater channel up thru behind the speaker grills followoing the path of the old paper heater hoses, that is a source of leaks, and you will be then routing you hose up over the dash near teh fuel tank, and you will need more anlged metallic couplings to make the needed bends up there, again leak potential, and that hot water, even though behind the dash int eh gas tank area will still drip (or gush) down on your feet if it fails via the many penitrations under the dash.
try to keep it all under the car with tough rubber, valid points were made about bleeding air out with the behind the dash route. you will want to add multible bleed valves otherwise (royal pain) yes the wheel well option will work too, however you have to keep teh pipe close and tight to avaoid tire rubbing (make extra room for future bigger tires)
pay very care full attention to pipe diameters, dont go too small or you will have flow issues, this is a long run, too small a diameter with too powerful and engien will spell probelms (plan ahead for future is you ever want to pump up or upgrade you water cooled motor, you want ot make sure you cooling lines are already big enough. go over kill in diameter as much you can.
200F fluid circulating inches form you feet is not a nice thing on a hot day ever.