Mark -
AFAIK all of the 70-76 MY OE alloy lugs were all zinc - but more of a semi-shiny finish, than some zinc plating that is almost chrome-like. They did sell black plastic lug caps back in the 74-76 MYs for some factory wheel set-ups IIRC.
Click to view attachment Click to view attachment Click to view attachment Click to view attachment.
Porsche may have started to substitute the black oxide finished ones later - after 914 production ended - when they started using the black lugs on the 911/930 black 5-lug Fuchs, & selling those as a superceded part/part no.
There are two nailed topics at O&H with good pix for reference on this - one being the "Wheels & Tires" topic -
http://www.914world.com/bbs2/index.php?showtopic=74857...& the other being The few, the rare...." one which featured Steve G's/smg's all original Sahara Biege `73 914-2.0 in the pic below.
http://www.914world.com/bbs2/index.php?showtopic=101921Click to view attachment ^-- The semi-shiny finish blends better with the correct OE "frosted" semi-shiny background finish on the wheels. --^.
Hope this helps!