From the couple letters I can see in the first picture, the casting looks to be 021-101-371S. Which is for a 1.8 head.
Click to view attachmentNow that I can see the pictures on a full screen (was on my phone last night), the valve retainers
ARE stock.
And after lightening them significantly in Photoshop, the combustion chamber photos are 1.8 shape.
Click to view attachmentI also don't see any machining marks on the ring around the cylinder seat. This area gets machined when the cylinder seating surface gets machined.
Click to view attachmentAlso, the divot/dot on the exhaust valve means they're stock sodium-filled valves, which are very hard to find out and of dubious benefit. Most rebuilders don't spend the time to find sodium-filled valves when they rebuild because it's only worth the effort for a specific reason (someone demands them in their engine or some race-rule-book says they need stock valves).
So the bottom line is that they look like an original, untouched set of 1.8 heads.
From what' I'm seeing in the pictures and what I'm reading of your description, my intuition and experience leads me to believe that you, unfortunately, pulled and disassembled the motor for nothing.
Popping from the carbs is an indicator of lean tuning (not enough fuel). Overheating can also come with lean running. I think the problems you were experience had more to do with your carbs than the motor.
But now you have it apart, so you should do a quick refresh on the heads. Get the surface flycut, get the valves ground. Then remove the cylinder base gaskets (between the case and cylinders, no it's not necessary) as well as the head gaskets if you have them. These two gaskets being removed with bump the compression slightly, as will flycutting the heads. This will bring up your compression numbers slightly and add a bit of performance.
You could just reassemble as well. But if nothing else, remove the head gaskets if there are any.
Post more (WELL LIT!) pictures of the rest of the engine as it sits now. I may be able to interpret more about your setup and help choose what the best next step is.