If they haven't moved in 20 years you'll either need to:
1) Put them back in the car and pump them out with brake fluid or,
2) Using a hydraulic grease gun, remove the nozzle, screw the threaded portion into the caliper and pump them out with grease.
You need a fluid to get pistons out that have been in there for 20 years. Air compresses too much.
You'll also need some bore plugs/stops/covers/seals (whatever you want to call them). Once a piston is out you need to seal that bore so you can get the other out. You can make the seals out of some heavy steel stock and some rubber washers which can be had at Lowe's. You use common C-Clamps to hold them into place while you pump out the other piston. It takes a tremendous amount of pressure to get those out.
Have fun
Welcome to the club