one on every wheel normally means it's a locking lug bolt...if a your socket fits (looks like a 17mm instead of 19mm), then you should be able to remove it....
seeing the rust you have on the other lug nut, they all might be tough to remove.....
it could just be that the PO only had 12 regular bolts and used something from another car such as an Audi...played it "safe" by installing the mismatched bolts on each wheel