QUOTE(MattR @ May 20 2006, 11:49 PM)
Too big of brakes in the rear will cause the rears to lock up before the fronts (not good). So more meat in the rear will help prevent that, so you can increase your total braking force.
Not just "more meat", but more rear mass, too. Traction is a function of vertical force on the tire, as well as tire construction, compound, and size. If a car has, say, a 65% rear weight bias static, and the same CG height, then less total weight will be transferred off the rears than they would be if the car started with a 50% weight bias. Thus, the rears will be able to contribute more to overall braking before lockup with the 65% static bias than they would with the 50% static bias. This is true even with equal-sized tires front and rear.
To size the split between front and rear calipers, you need to calculate the dynamic weight bias (bias under maximum braking). You can approximate the max braking G as 1.0 to start with (most decent tires will allow this). You'll have to know the CG at your car's ride height, and you'll need to know the static weight bias. The weight percentages you end up with front/rear will tell you (roughly) what brake bias split you want to start with.
An adjustable proportioning valve would be very important to such experimentation (and easier than doing the calculations, too). If you fit rear calipers that are too big, you just dial them down with the prop valve until you get the fronts locking a bit earlier than the rears.
You'd also want to test braking into turns, as this will also change the weight bias numbers. Much of the weight will move to the outside front tire, with the outside rear being the second highest loaded. You can basically ignore the inside tires for this test, as locking either of them won't (generally) cause any huge dynamic changes.